Eduqas A Level Chemistry

Eduqas A Level Chemistry PI4.2 Entropy and Feasibility of Reactions Exam Questions

Free Eduqas A Level Chemistry exam questions on PI4.2 Entropy and Feasibility of Reactions, with mark schemes. Covers entropy, Gibbs free energy and feasibility.

PI4.2 Entropy and Feasibility of Reactions exam questions

1 question pack of real past exam questions with its mark scheme. Answer every question without notes, then mark your answers line by line against the mark scheme.

PI4.2 Entropy and Feasibility of ReactionsQuestions and mark scheme
A Level Chemistry Flashcards StemUp mark scheme flashcards A Level Chemistry Flashcards Every answer is written in mark scheme wording, so you learn exactly what examiners give marks for. Pick your exam board, then test yourself with the questions on this page. View flashcards

About Eduqas A Level Chemistry PI4.2 Entropy and Feasibility of Reactions

This topic explains why reactions happen.

What you need to know

  • Entropy A measure of disorder; gases have higher entropy than liquids and solids.
  • Entropy change ΔS = ΣS(products) − ΣS(reactants).
  • Gibbs free energy ΔG = ΔH − TΔS; a reaction is feasible when ΔG ≤ 0.
  • Temperature Find the temperature at which a reaction becomes feasible.

Common mistakes in PI4.2 Entropy and Feasibility of Reactions

  • Forgetting to convert ΔS from J to kJ.
  • Saying feasible reactions always occur quickly.
  • Getting the sign of ΔS wrong for gas production.

Try three PI4.2 Entropy and Feasibility of Reactions exam-style questions

1. Calculate ΔG at 298 K if ΔH = +50 kJ mol⁻¹ and ΔS = +200 J K⁻¹ mol⁻¹. (2 marks)

Show the mark scheme answer

ΔG = 50 − 298 x 0.200 (1) = −9.6 kJ mol⁻¹ (1).

2. Explain why ΔS is positive for CaCO₃ → CaO + CO₂. (1 mark)

Show the mark scheme answer

A gas is formed from a solid, increasing disorder.

3. State the condition for feasibility. (1 mark)

Show the mark scheme answer

ΔG ≤ 0.

PI4.2 Entropy and Feasibility of Reactions FAQs

What does Entropy and Feasibility cover?

Entropy, Gibbs free energy and predicting feasibility.

What units are used?

ΔH in kJ mol⁻¹, ΔS in J K⁻¹ mol⁻¹, so convert before combining.

Can kinetics stop a feasible reaction?

Yes, if the activation energy is high.